Drastic difference in the photo-driven hydrogenation reactions of ruthenium complexes containing NAD model ligands.
نویسندگان
چکیده
Successful control of photo-driven NAD(+)/NADH type hydrogenation reactions in ruthenium complexes has been accomplished by using a new NAD(+) model ligand with modulated distortion of the ligand taking advantage of the substituent effect.
منابع مشابه
Synthesis and Characterization of Organosoluble Ruthenium(ii) Complexes Bearing Schiff Base Ligands: Efficient Reusable Catalyst for the Hydrogenation Reactions
Department of Chemistry, Kongunadu Arts and Science College, Coimbatore – 641029, India Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore – 641020, India. ABSTRACT: Six new organosoluble ruthenium(II) complexes bearing dibasic tetradentate Schiff base ligands of the general formula [Ru(CO)(PPh3)(L)] (where L = dibasic t...
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Hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) was studied by using mono- and bidentate p-cymene ruthenium(ii) N-heterocyclic carbene (NHC) complexes as catalyst precursors. In water, all complexes were found to be reduced in situ to form ruthenium nanoparticles (RuNPs) with a high hydrogenation activity. In organic solvents, complexes with monodentate NHC ligands also formed nan...
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عنوان ژورنال:
- Chemical communications
دوره 48 12 شماره
صفحات -
تاریخ انتشار 2012